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Pretty much gotta be the Hulk.
Whenever you look at the history of things that have defeated Hulk in the comics, it's basically metaphysical entities who can alter matter or stifle Hulk's brain. The Terminator is very tough to defeat, but Hulk is completely invulnerable.
I went through a comic book phase for a few months about eight years ago and read this thing called World War Hulk, where Hulk basically invades the earth and every superhero you've ever seen in Marvel gets crushed and defeated trying to take him down. He was so powerful, the author basically had to invent this guy called "The Sentry," who had the physical power of several suns.
Sentry fought Hulk to a standstill and leveled an entire metropolis doing so. They fought so hard, they both reverted to their regular-human form, and Bruce Banner killed him. I'm pretty sure that's the only time in comic book history that Hulk's been physically challenged. Every other time he was beaten, was by a god.
So the Hulk can be worn down. And he can be defeated. But by entities that have to have god-like entities. Not simply a super robot.
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